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Head & Shoulders I Refresh Dandruff Shampoo-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: ShampooStructure such as solid, liquid, aerosol etc.
Form: liquidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 14, 2024P.O. Box 599
Cincinnati OH 45201
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 013463-41-7 -- 1 T, Xi, N -- -- -- -- 007732-18-5 -- -- -- -- -- 032612-48-9 -- -- -- -- -- 002235-54-3 -- -- -- -- -- 000137-16-6 -- -- -- -- -- 000627-83-8 -- -- -- -- -- 009006-65-9 -- -- -- -- -- 007757-82-6 -- -- -- -- -- 007647-14-5 -- -- -- -- -- 000000-00-1 -- -- -- -- -- 006440-58-0 -- -- -- -- -- 007558-79-4 -- -- -- -- -- 007632-05-5 -- -- -- -- -- 000112-53-8 -- -- -- -- -- 025322-68-3 -- -- -- -- -- 081859-24-7 -- -- -- -- -- 003844-45-9 -- -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.UN Global Harmonization Classification
Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)Zinc pyrithione
013463-41-7
236-671-31 No H301, H331, H318, H400 P264, P270, P261, P271, P280, P273, P301+P310, P330, P304+P340, P311, P305+P351+P338, P310, P501 No No Water
007732-18-5
231-791-2-- No -- -- -- No No Ammonium laureth sulfate
032612-48-9
---- No -- -- -- No No Ammonium lauryl sulfate
002235-54-3
218-793-9-- No -- -- -- No No Sodium lauroyl sarcosinate
000137-16-6
205-281-5-- No H330, H315, H318 P260, P271, P284, P304+P340, P310, P320, P403+P233, P405, P501, P264, P280, P302+P352, P321, P332+P313, P362, P305+P351+P338 No No Glycol distearate
000627-83-8
211-014-3-- No -- -- -- No No Dimethicone
009006-65-9
---- No -- -- -- No No Sodium sulfate
007757-82-6
231-820-9-- No -- P262 -- No No Sodium chloride
007647-14-5
231-598-3-- No -- -- -- No No Fragrance(s)/perfume(s)
000000-00-1
---- No -- -- -- No No DMDM hydantoin
006440-58-0
229-222-8-- No H302 P301+P312 No No Disodium phosphate
007558-79-4
231-448-7-- No -- -- -- No No Sodium phosphate
007632-05-5
---- No -- -- -- No No Lauryl alcohol
000112-53-8
203-982-0-- No H319, H400, H411 P264, P280, P305+P351+P338, P337+P313, P273, P391, P501 No No Glycols, polyethylene
025322-68-3
500-038-2-- No -- -- -- No No Polymer JR
081859-24-7
617-262-2-- No -- -- -- No No Acid Blue 9
003844-45-9
223-339-8-- No -- -- -- No No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H301 : Toxic if swallowedH302 : Harmful if swallowedH315 : Causes skin irritationH318 : Causes serious eye damageH319 : Causes serious eye irritationH330 : Fatal if inhaledH331 : Toxic if inhaledH400 : Very toxic to aquatic lifeH411 : Toxic to aquatic life with long lasting effects
- P260 : Do not breathe dust/fume/gas/mist/vapours/sprayP261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP262 : Do not get in eyes, on skin, or on clothingP264 : Wash … thoroughly after handlingP270 : Do not eat, drink or smoke when using this productP271 : Use only outdoors or in a well-ventilated areaP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP284 : Wear respiratory protectionP310 : Immediately call a POISON CENTER or doctor/physicianP311 : Call a POISON CENTER or doctor/physicianP320 : Specific treatment is urgent (see … on this label)P321 : Specific treatment (see … on this label)P330 : Rinse mouthP362 : Take off contaminated clothing and wash before reuseP391 : Collect spillageP301+P310 : IF SWALLOWED: Immediately call a POISON CENTER or doctor/physicianP301+P312 : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellP302+P352 : IF ON SKIN: Wash with soap and waterP304+P340 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP332+P313 : If skin irritation occurs: Get medical advice/attentionP337+P313 : Get medical advice/attentionP405 : Store locked upP501 : Dispose of contents/container to
- GHS05 : CorrosiveGHS06 : ToxicGHS07 : IrritantGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :October 01, 1998 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATINGN N N -
SVHC declaration
This product does not contain any Substances of Very High Concern (SVHC).
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Acute health effects
From MSDS ROUTES OF ENTRY Eye, oral, skin HEALTH HAZARDS (ACUTE AND CHRONIC) For external use only. Avoid eye contact. If eye contact occurs, rinse eyes thoroughly with water. If condition worsens or does not improve after regular use of this product as directed, consult a Doctor. If swallowed, get medical help right away. SIGNS OF SYMPTOMS OF EXPOSURE: May cause nausea if ingested. Eye contact may cause redness / irritation. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: N/A -
Chronic health effects
From MSDS Chronic health hazards same as acute hazards. -
Carcinogenicity
The manufacturer's Material Safety Data Sheet (MSDS) does not state whether the ingredients are considered carcinogens or potential carcinogens. -
Handling information
From MSDS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: No special precautions. -
Disposal information
From MSDS Non-hazardous waste. -
First Aid
From MSDS If swallowed, get medical help right away. If eye contact occurs, rinse eyes thoroughly with water. If condition worsens or does not improve after regular use of this product as directed, consult a Doctor.
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